Search results for "Q band"

Theoretical study of the electronic spectrum of magnesium-porphyrin

1999

Multiconfigurational self-consistent field (SCF) and second order perturbation methods have been used to study the electronic spectrum of magnesium-porphyrin (MgP). An extended ANO-type basis set including polarization functions on all heavy atoms has been used. Four allowed singlet states of E1u symmetry have been computed and in addition a number of forbidden transitions and a few triplet states. The results lead to a consistent interpretation of the electronic spectrum, where the Q band contains one transition, the B band two, and the N band one. The computed transition energies are consistently between 0.1 and 0.5 too low compared to the measured band maxima. The source of the discrepan…

Deduction of the oxidation degree of the group A15 elements at the phthalocyanines on the basis of the Q band

2017

Long-term ozone exposure of potato: Free radical content and leaf injury analysed by Q-band ESR spectroscopy and image analysis

2008

This paper presents Q-band electron spin resonance (ESR) studies on free radicals (FR) generated in potato leaves exposed to different O(3) levels in open-top chambers (OTC), together with a quantitative study of the relationship between FR signal intensity and area of potato leaf damage. The advantages of Q-band when compared to X-band ESR spectroscopy are analysed, the main advantage being an absence of overlapping between Mn(II) and FR signals, allowing a quantitative study of FR signal intensity. This study also reports on a graphical method developed to quantitatively measure the damaged area on leaves caused by ozone exposure. Results indicate a direct relationship between FR signal i…

Core-shifts and proper-motion constraints in the S5 polar cap sample at the 15 and 43 GHz bands

2018

We have studied a complete radio sample of active galactic nuclei with the very-long-baseline-interferometry (VLBI) technique and for the first time successfully obtained high-precision phase-delay astrometry atQband (43 GHz) from observations acquired in 2010. We have compared our astrometric results with those obtained with the same technique atUband (15 GHz) from data collected in 2000. The differences in source separations among all the source pairs observed in common at the two epochs are compatible at the 1σlevel betweenUandQbands. With the benefit of quasi-simultaneousUandQband observations in 2010, we have studied chromatic effects (core-shift) at the radio source cores with three d…